Transmittance Explained

Electromagnetic radiation can be affected in several ways by the medium in which it propagates.  It can be scattered, absorbed, and reflected and refracted at discontinuities in the medium.  This page is an overview of the last 3. The transmittance of a material and any surfaces is its effectiveness in transmitting radiant energy; the fraction of the initial (incident) radiation which propagates to a location of interest (often an observation location). This may be described by the transmission coefficient.

Surface transmittance

Hemispherical transmittance

Hemispherical transmittance of a surface, denoted T, is defined as[1]

T=

t
\Phi
e
i
\Phi
e

,

where

Hemispheric transmittance may be calculated as an integral over the directional transmittance described below.

Spectral hemispherical transmittance

Spectral hemispherical transmittance in frequency and spectral hemispherical transmittance in wavelength of a surface, denoted Tν and Tλ respectively, are defined as

T\nu=

t
\Phi
e,\nu
i
\Phi
e,\nu

,

Tλ=

t
\Phi
e,λ
i
\Phi
e,λ

,

where

Directional transmittance

Directional transmittance of a surface, denoted TΩ, is defined as

T\Omega=

t
L
e,\Omega
i
L
e,\Omega

,

where

Spectral directional transmittance

Spectral directional transmittance in frequency and spectral directional transmittance in wavelength of a surface, denoted Tν,Ω and Tλ,Ω respectively, are defined as

T\nu,\Omega=

t
L
e,\Omega,\nu
i
L
e,\Omega,\nu

,

Tλ,\Omega=

t
L
e,\Omega,λ
i
L
e,\Omega,λ

,

where

Luminous transmittance

In the field of photometry (optics), the luminous transmittance of a filter is a measure of the amount of luminous flux or intensity transmitted by an optical filter. It is generally defined in terms of a standard illuminant (e.g. Illuminant A, Iluminant C, or Illuminant E). The luminous transmittance with respect to the standard illuminant is defined as:

Tlum=

infty
\intI(λ)T(λ)V(λ)dλ
0
infty
\intI(λ)V(λ)dλ
0

where:

I(λ)

is the spectral radiant flux or intensity of the standard illuminant (unspecified magnitude).

T(λ)

is the spectral transmittance of the filter

V(λ)

is the luminous efficiency function

The luminous transmittance is independent of the magnitude of the flux or intensity of the standard illuminant used to measure it, and is a dimensionless quantity.

Internal transmittance

Optical depth

By definition, internal transmittance is related to optical depth and to absorbance as

T=e-\tau=10-A,

where

Beer–Lambert law

See main article: Beer–Lambert law.

The Beer–Lambert law states that, for N attenuating species in the material sample,

\tau=

N
\sum
i=1

\taui=

N
\sum
i=1

\sigmai

\ell
\int
0

ni(z)dz,

A=

N
\sum
i=1

Ai=

N
\sum
i=1

\varepsiloni

\ell
\int
0

ci(z)dz,

where

Attenuation cross section and molar attenuation coefficient are related by

\varepsiloni=

NA
ln{10
}\,\sigma_i,and number density and amount concentration by

ci=

ni
NA

,

where NA is the Avogadro constant.

In case of uniform attenuation, these relations become

\tau=

N
\sum
i=1

\sigmaini\ell,

A=

N
\sum
i=1

\varepsilonici\ell.

Cases of non-uniform attenuation occur in atmospheric science applications and radiation shielding theory for instance.

See also

Notes and References

  1. Web site: August 1, 2022 . Thermal insulation — Heat transfer by radiation — Vocabulary . February 12, 2025 . ISO 9288:2022 . ISO catalogue.