Elpidite
A valid IMA mineral species - grandfathered
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About Elpidite
Formula:
Na2ZrSi6O15 · 3H2O
Colour:
Colorless, white, gray, yellowish, orange, brown, beige
Lustre:
Vitreous, Waxy, Silky, Dull
Hardness:
5
Specific Gravity:
2.52 - 2.62
Crystal System:
Orthorhombic
Name:
The name derives from the Greek word for hope, representing the hope that other interesting minerals would be found at the type locality.
Dimorph of:
A highly hydrated variety, bearing large admixture of hydronium ions, is known (Zubkova et al. 2021).
Unique Identifiers
Mindat ID:
1370
Long-form identifier:
mindat:1:1:1370:9
IMA Classification of Elpidite
Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Na2Zr4+Si6O15·3H2O
First published:
1894
Classification of Elpidite
9.DG.65
9 : SILICATES (Germanates)
D : Inosilicates
G : Inosilicates with 3-periodic single and multiple chains
9 : SILICATES (Germanates)
D : Inosilicates
G : Inosilicates with 3-periodic single and multiple chains
72.5.4.2
72 : PHYLLOSILICATES Two-Dimensional Infinite Sheets with Other Than Six-Membered Rings
5 : Two-Dimensional Infinite Sheets with Other Than Six-Membered Rings with corrugated and complex layers
72 : PHYLLOSILICATES Two-Dimensional Infinite Sheets with Other Than Six-Membered Rings
5 : Two-Dimensional Infinite Sheets with Other Than Six-Membered Rings with corrugated and complex layers
14.10.9
14 : Silicates not Containing Aluminum
10 : Silicates of Zr or Hf
14 : Silicates not Containing Aluminum
10 : Silicates of Zr or Hf
Mineral Symbols
As of 2021 there are now IMAâCNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Epd | IMAâCNMNC | Warr, L.N. (2021). IMAâCNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Pronunciation of Elpidite
Pronunciation:
| Play | Recorded by | Country |
|---|---|---|
| Jolyon Ralph | United Kingdom |
Physical Properties of Elpidite
Vitreous, Waxy, Silky, Dull
Transparency:
Transparent, Translucent, Opaque
Colour:
Colorless, white, gray, yellowish, orange, brown, beige
Hardness:
5 on Mohs scale
Cleavage:
Perfect
On {110}
On {110}
Fracture:
Splintery
Density:
2.52 - 2.62 g/cm3 (Measured) 2.59 g/cm3 (Calculated)
Optical Data of Elpidite
Type:
Biaxial (+)
RI values:
nα = 1.56 nβ = 1.565 - 1.569 nγ = 1.574
Max. Birefringence:
δ = 0.014
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 ”m thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 ”m thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
Moderate (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).
Relative to Canada balsam mounting medium (n ≈ 1.537).
This shows the grain boundary and Becke line effect under plane-polarised
light, based on the contrast between this mineral's average refractive
index and the mounting medium. It does not take into account mineral
colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure
- the conoscopic view for a grain cut perpendicular to the acute bisectrix, using
this mineral's 2V. The two small white dots mark the melatopes - the points
where the two optic axes emerge - and are shown only when they fall within the
field of view. The coloured bands are isochromatics, and the dark bands are
isogyres.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
No measured or calculated 2V is on file for this mineral, so the value used here (90°) is estimated from its recorded refractive indices and optic sign, not from a direct 2V measurement.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
No measured or calculated 2V is on file for this mineral, so the value used here (90°) is estimated from its recorded refractive indices and optic sign, not from a direct 2V measurement.
Dispersion:
r < v moderate
Optical Extinction:
X = c; Y = b; Z = a.
Chemistry of Elpidite
Mindat Formula:
Na2ZrSi6O15 · 3H2O
Element Weights:
Common Impurities:
Ti,Nb,Ca,K,F,Cl
Crystallography of Elpidite
Crystal System:
Orthorhombic
Cell Parameters:
a = 7.29 Å, b = 14.3 Å, c = 7.03 Å
Ratio:
a:b:c = 0.51 : 1 : 0.492
Unit Cell V:
732.86 Ă
Âł (Calculated from Unit Cell)
Comment:
Space group of the hydrated (H3O)-bearing) variety is Pma2
Crystallographic forms of Elpidite
Crystal Atlas:
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Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0000303 | Elpidite | Cannillo E, Rossi G, Ungaretti L (1973) The crystal structure of elpidite American Mineralogist 58 106-109 | ![]() | 1973 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Loading XRD data...
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 3.26 Ă | (100) |
| 3.12 Ă | (70) |
| 1.945 Ă | (70) |
| 1.759 Ă | (70) |
| 1.590 Ă | (70) |
| 1.352 Ă | (70) |
| 1.492 Ă | (60) |
Comments:
NarssĂąrssuk pegmatite, Greenland.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 4b: Highly evolved igneous rocks | >3.0 |
| 34 : Complex granite pegmatites | |
| 35 : Ultra-alkali and agpaitic igneous rocks |
Type Occurrence of Elpidite
Place of Conservation of Type Material:
University of Copenhagen, Copenhagen, Denmark.
Other Language Names for Elpidite
Dutch:Elpidiet
German:Elpidit
Russian:ĐĐ»ŃпОЎОŃ
Simplified Chinese:æé éçł
çș€çĄ éé çł
é éçł
çș€çĄ éé çł
é éçł
Spanish:Elpidita
Traditional Chinese:æééŻçł
çșçœéŻéçł
ééŻçł
çșçœéŻéçł
ééŻçł
Varieties of Elpidite
| Calcium-bearing Elpidite | High-temperature elpidite of magmatic origin typical for agpaitic granites. Usually enriched in Ca; has orange colour in difference from secondary hydrothermal low-temperature elpidites from nepheline-syenites. |
Common Associates
Associations Based on Photo Data:
| 82 photos of Elpidite associated with Aegirine | NaFe3+Si2O6 |
| 80 photos of Elpidite associated with Albite | Na(AlSi3O8) |
| 69 photos of Elpidite associated with Rhodochrosite | MnCO3 |
| 57 photos of Elpidite associated with Microcline | K(AlSi3O8) |
| 37 photos of Elpidite associated with Fluorite | CaF2 |
| 31 photos of Elpidite associated with Calcite | CaCO3 |
| 28 photos of Elpidite associated with Catapleiite | Na2Zr(Si3O9) · 2H2O |
| 28 photos of Elpidite associated with Nenadkevichite | (Na,â»)8Nb4(Si4O12)2(O,OH)4 · 8H2O |
| 27 photos of Elpidite associated with Quartz | SiO2 |
| 24 photos of Elpidite associated with Leifite | (Na,H2O)Na6[Be2Al2(Al,Si)Si15O39]F2 |
Related Minerals - Strunz-mindat Grouping
| 9.DG. | Barrydawsonite-(Y) | Na1.5Y0.5CaSi3O8(OH) |
| 9.DG. | Paratobermorite | Ca5AlSi5O16(OH) · 5H2O |
| 9.DG. | Calcinaksite | KNaCa(Si4O10) · H2O |
| 9.DG. | Alvesite | NaKZrSi6O15 · 2H2O |
| 9.DG.02 | Steedeite | NaMn2[Si3BO9](OH)2 |
| 9.DG.02 | Nolzeite | NaMn2[Si3BO9](OH)2 · 2H2O |
| 9.DG.05 | Murakamiite | LiCa2Si3O8(OH) |
| 9.DG.05 | Serandite | NaMn2+2Si3O8(OH) |
| 9.DG.05 | Bustamite | CaMn2+(Si2O6) |
| 9.DG.05 | Pectolite | NaCa2Si3O8(OH) |
| 9.DG.05 | Tanohataite | LiMn2Si3O8(OH) |
| 9.DG.05 | Dalnegorskite | Ca5Mn2+(Si3O9)2 |
| 9.DG.05 | 'Wollastonite-1A' | CaSiO3 |
| 9.DG.05 | Wollastonite | Ca3(Si3O9) |
| 9.DG.05 | Ferrobustamite | CaFe2+(Si2O6) |
| 9.DG.05 | Schizolite | NaCaMnSi3O8(OH) |
| 9.DG.07 | Cascandite | CaScSi3O8(OH) |
| 9.DG.08 | PlombiÚrite | Ca5Si6O16(OH)2 · 7H2O |
| 9.DG.10 | Clinotobermorite | Ca5Si6O17 · 5H2O |
| 9.DG.10 | Riversideite | Ca5Si6O16(OH)2 · 2H2O |
| 9.DG.10 | Tobermorite | Ca5Si6O17 · 5H2O |
| 9.DG.12 | Jusite | Na2Ca15Al4Si16O54 · 17H2O |
| 9.DG.12 | Kenotobermorite | Ca4Si6O15(OH)2 · 5H2O |
| 9.DG.15 | Foshagite | Ca4(Si3O9)(OH)2 |
| 9.DG.20 | Jennite | Ca9(Si3O9)2(OH)8 · 8H2O |
| 9.DG.20 | Kamenevite | K2TiSi3O9 · H2O |
| 9.DG.25 | Paraumbite | K3Zr2H(Si3O9)2 · nH2O |
| 9.DG.25 | Umbite | K2(Zr,Ti)Si3O9 · H2O |
| 9.DG.30 | SĂžrensenite | Na4SnBe2Si6O16(OH)4 |
| 9.DG.32 | Escheite | Ca2NaMnTi5[Si12O34]O2(OH)3 · 12H2O |
| 9.DG.35 | Xonotlite | Ca6(Si6O17)(OH)2 |
| 9.DG.40 | Hillebrandite | Ca2(SiO3)(OH)2 |
| 9.DG.45 | Zorite | Na8(Ti,Nb)5(Si6O17)2(OH,O)5 · 14H2O |
| 9.DG.45 | Chivruaiite | Ca4(Ti,Nb)5(Si6O17)2(OH,O)5 · 13-14H2O |
| 9.DG.50 | Haineaultite | (Na,Ca)5Ca(Ti,Nb)5(Si6O17)2(OH,F)8 · 5H2O |
| 9.DG.55 | Epididymite | Na2Be2Si6O15 · H2O |
| 9.DG.60 | Eudidymite | Na2Be2Si6O15 · H2O |
| 9.DG.65 | Patynite | NaKCa4[Si9O23] |
| 9.DG.67 | Whelanite | Cu2+2Ca6[Si6O17(OH)](CO3)(OH)3 · 2H2O |
| 9.DG.70 | Enricofrancoite | KNaCaSi4O10 |
| 9.DG.70 | Yusupovite | Na2Zr(Si6O15) · 2.5H2O |
| 9.DG.70 | Litidionite | KNaCuSi4O10 |
| 9.DG.70 | Fenaksite | (K,Na)4(Fe,Mn)2(Si4O10)2(OH,F) |
| 9.DG.70 | Manaksite | KNaMnSi4O10 |
| 9.DG.75 | Senkevichite | CsKNaCa2TiO[Si7O18](OH) |
| 9.DG.75 | Tinaksite | K2Na(Ca,Mn2+)2TiO[Si7O18(OH)] |
| 9.DG.75 | Tokkoite | K2Ca4[Si7O18(OH)](OH,F) |
| 9.DG.80 | Fluorcanasite | K3Na3Ca5Si12O30F4 · H2O |
| 9.DG.80 | Canasite | K3Na3Ca5Si12O30(OH)4 |
| 9.DG.85 | Miserite | K1.5-x(Ca,Y,REE)5(Si6O15)(Si2O7)(OH,F)2 · yH2O |
| 9.DG.90 | Frankamenite | K3Na3Ca5(Si12O30)(F,OH)4 · H2O |
| 9.DG.92 | Charoite | (K,Sr)15-16(Ca,Na)32[Si6O11(O,OH)6]2[Si12O18(O,OH)12]2[Si17O25(O,OH)18]2(OH,F)4 · ~3H2O |
| 9.DG.95 | Yuksporite | K4(Ca,Na)14(Sr,Ba)2(â»,Mn,Fe)(Ti,Nb)4(O,OH)4(Si6O17)2(Si2O7)3(H2O,OH)3 |
| 9.DG.97 | Eveslogite | (Na,K,Ca,Sr,Ba)48 [(Ti,Nb,Mn,Fe2+)12Si48O144(OH)12](F,OH,Cl)14 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Elpidite
mindat.org URL:
https://www.mindat.org/min-1370.html
Please feel free to link to this page.
Please feel free to link to this page.
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References for Elpidite
Reference List:
Chao, G. Y. (1967) Leucophanite, elpidite, and narsarsukite from the Desourdy quarry, Mont St. Hilaire, Quebec. The Canadian Mineralogist, 9 (2).
Cannillo, Elio, Rossi, Guiseppe, Ungaretti, Luciano (1973) The crystal structure of elpidite. American Mineralogist, 58 (1-2) 106-109
Currie, K. L., Zaleski, E. (1985) The relative stability of elpidite and vlasovite: a P-T indicator for peralkaline rocks. The Canadian Mineralogist, 23 (4) 577-582
Merlino, Stefano, Bonaccorsi, Elena (2008) Double wollastonite chains: topological/conformational varieties, polytypic forms, isotypic compounds. Zeitschrift fĂŒr Kristallographie - Crystalline Materials, 223 (1-2). 85-97 doi:10.1524/zkri.2008.0006
Grigorâeva, A. A., Zubkova, N. V., Pekov, I. V., Kolitsch, U., Pushcharovsky, D. Yu., Vigasina, M. F., Giester, G., DordeviÄ, T., Tillmanns, E., Chukanov, N. V. (2011) Crystal chemistry of elpidite from Khan Bogdo (Mongolia) and its K- and Rb-exchanged forms. Crystallography Reports, 56 (5) 832-841 doi:10.1134/s1063774511050117
Nedelâko, V. V., Chukanov, N. V., Pekov, I. V. (2011) Dehydration kinetics of the microporous zirconosilicate elpidite. Inorganic Materials, 47 (5) 502-505 doi:10.1134/s0020168511050165
Zubkova, N. V., Ksenofontov, D. A., Kabalov, Yu. K., Chukanov, N. V., Nedelâko, V. V., Pekov, I. V., Pushcharovsky, D. Yu. (2011) Dehydration-induced structural transformations of the microporous zirconosilicate elpidite. Inorganic Materials, 47 (5) 506-512 doi:10.1134/s0020168511050232
Grice, Joel D., Rowe, Ralph, Poirier, Glenn (2015) Hydroterskite: A New Mineral Species From the Saint-Amable Sill, Quebec, and A Comparison With Terskite and Elpidite. The Canadian Mineralogist, 53 (5) 821-832 doi:10.3749/canmin.1400105
Cametti, Georgia, Armbruster, Thomas, Nagashima, Mariko (2016) Dehydration and thermal stability of elpidite: An in-situ single crystal X-ray diffraction study. Microporous and Mesoporous Materials, 227. 81-87 doi:10.1016/j.micromeso.2016.02.049
Zubkova, Natalia V., Pekov, Igor V., Chukanov, Nikita V., Yapaskurt, Vasiliy O., Turchkova, Anna G., Larikova, Tatiana S., Pushcharovsky, Dmitry Yu. (2021) A highly hydrated variety of elpidite from the Khibiny alkaline complex, Kola Peninsula, Russia. Mineralogical Magazine, 85 (4) 627-633 doi:10.1180/mgm.2020.96
Localities for Elpidite
Showing 82 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
â - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
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The
Poudrette quarry, Mont Saint-Hilaire, La Vallée-du-Richelieu RCM, Montérégie, Québec, Canada