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Arsendescloizite

A valid IMA mineral species
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About ArsendescloiziteHide

06738700017271921209883.jpg
Alfred Des Cloizeaux
Formula:
PbZn(AsO4)(OH)
Colour:
Pale yellow to deep green, greyish brown
Lustre:
Sub-Vitreous
Hardness:
4
Specific Gravity:
6.57 (Calculated)
Crystal System:
Orthorhombic
Name:
Named by Paul Keller and Pete J. Dunn in 1982 for being the arsenate analog of descloizite.
Adelite-Descloizite Group. Arsenate analogue of Descloizite.


Unique IdentifiersHide

Mindat ID:
356
Long-form identifier:
mindat:1:1:356:2

IMA Classification of ArsendescloiziteHide

Approved
IMA Formula:
Pb2+Zn2+As5+O4(OH)
Approval year:
1979
First published:
1982

Classification of ArsendescloiziteHide

8.BH.35

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
H : With medium-sized and large cations, (OH,etc.):RO4 = 1:1
Dana 7th ed.:
41.5.1.9
41.5.1.9

41 : ANHYDROUS PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
5 : (AB)2(XO4)Zq
20.5.6

20 : Arsenates (also arsenates with phosphate, but without other anions)
5 : Arsenates of Ti and Pb

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
AdczIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ArsendescloiziteHide

Sub-Vitreous
Transparency:
Transparent
Colour:
Pale yellow to deep green, greyish brown
Comment:
Colour depending on impurity contents, especially Cu.
Streak:
White
Hardness:
Density:
6.57 g/cm3 (Calculated)

Optical Data of ArsendescloiziteHide

Type:
Biaxial (-)
RI values:
nα = 1.990 nβ = 2.030 nγ = 2.035
2V:
Measured: 30° , Calculated: 38°
Birefringence:
0.045
Max. Birefringence:
δ = 0.045
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r > v
Optical Extinction:
XYZ = bac
Pleochroism:
Non-pleochroic

Chemistry of ArsendescloiziteHide

Mindat Formula:
PbZn(AsO4)(OH)
Element Weights:
Element% weight
Pb48.354 %
O18.669 %
As17.484 %
Zn15.258 %
H0.235 %

Calculated from ideal end-member formula.
Pb
O
As
Zn
H

Crystallography of ArsendescloiziteHide

Crystal System:
Orthorhombic
Class (H-M):
222 - Disphenoidal
Space Group:
P212121
Setting:
P212121
Cell Parameters:
a = 6.075 Å, b = 9.358 Å, c = 7.634 Å
Ratio:
a:b:c = 0.649 : 1 : 0.816
Unit Cell V:
433.99 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Platy to wedge-shaped crystals. Platy {100} to 1 mm; also with {101}. {110}, {100}, {111}.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0014924ArsendescloiziteKeller P, Lissner F, Schleid T (2003) The crystal structure of arsendescloizite, PbZn(OH)[AsO4], from Tsumeb (Namibia) Neues Jahrbuch fur Mineralogie, Monatshefte 2003 374-3842003Tsumeb, Namibia0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
4.23 Å(60)
3.23 Å(100)
2.88 Å(100)
2.60 Å(80)
2.09 Å(60)
1.656 Å(60)
1.559 Å(80)
Comments:
ICDD 35-668

Geological EnvironmentHide

Paragenetic Mode(s):

Type Occurrence of ArsendescloiziteHide

Place of Conservation of Type Material:
Institut für Mineralogie und Kristallchemie, Stuttgart, Germany, number NM 08.
National Museum of Natural History, Washington, D.C., USA, number 148303.
Archiv der Universität Stuttgart, Stuttgart, Germany, number TM-79.30-B76.
Geological Setting of Type Material:
Oxidized zone of a polymetallic ore arsenic-bearing sulfide deposit
Associated Minerals at Type Locality:

Synonyms of ArsendescloiziteHide

Other Language Names for ArsendescloiziteHide

Relationship of Arsendescloizite to other SpeciesHide

Other Members of Adelite-Descloizite Group:
AdeliteCaMg(AsO4)(OH)Orth. 222 : P212121
AustiniteCaZn(AsO4)(OH)Orth. 222 : P212121
ČechitePbFe2+(VO4)(OH)Orth. mmm(2/m2/m2/m)
CobaltaustiniteCaCo(AsO4)(OH)Orth. 222 : P212121
ConichalciteCaCu(AsO4)(OH)Orth. 222 : P212121
DescloizitePbZn(VO4)(OH)Orth. mmm(2/m2/m2/m) : Pnma
DuftitePbCu(AsO4)(OH)Orth. 222 : P212121
'Duftite-alpha'PbCu(AsO4)(OH)
GottlobiteCaMg(VO4)(OH)Orth. 222 : P212121
HermannroseiteCaCu(PO4)(OH)Orth. 222 : P212121
MottramitePbCu(VO4)(OH)Orth. mmm(2/m2/m2/m) : Pnma
NickelaustiniteCaNi(AsO4)(OH)Orth. 222 : P212121
PlumbogottlobitePbMg(VO4)(OH)Orth. mmm(2/m2/m2/m) : Pnma
PyrobelonitePbMn2+(VO4)(OH)Orth. mmm(2/m2/m2/m) : Pnma
TangeiteCaCu(VO4)(OH)Orth. 222 : P212121
'Unnamed (Pb-analogue of Nickelaustinite)'PbNi(AsO4)(OH)
VuagnatiteCaAl(SiO4)(OH)Orth. 222 : P212121

Common AssociatesHide

Associations Based on Photo Data:
20 photos of Arsendescloizite associated with MimetitePb5(AsO4)3Cl
15 photos of Arsendescloizite associated with CalciteCaCO3
5 photos of Arsendescloizite associated with 'Copper-bearing Austinite'Ca(Zn,Cu)(AsO4)(OH)
5 photos of Arsendescloizite associated with 'Copper-bearing Adamite'(Zn,Cu)2AsO4OH
4 photos of Arsendescloizite associated with ConichalciteCaCu(AsO4)(OH)
4 photos of Arsendescloizite associated with HemimorphiteZn4Si2O7(OH)2 · H2O
3 photos of Arsendescloizite associated with VanadinitePb5(VO4)3Cl
2 photos of Arsendescloizite associated with OjuelaiteZnFe3+2(AsO4)2(OH)2 · 4H2O
2 photos of Arsendescloizite associated with DescloizitePbZn(VO4)(OH)
2 photos of Arsendescloizite associated with AcanthiteAg2S

Related Minerals - Strunz-mindat GroupingHide

8.BH.PeterchiniteZn3Zn2(OH)6As[O3(OH)3]Mon. 2/m : B2/m
8.BH.ReznitskyiteCaMg(VO4)FMon. 2/m : B2/b
8.BH.PlumbogottlobitePbMg(VO4)(OH)Orth. mmm(2/m2/m2/m) : Pnma
8.BH.CuprozheshengitePb4CuZn2(AsO4)2(PO4)2(OH)2Tric. 1 : P1
8.BH.ZheshengitePb4ZnZn2(AsO4)2(PO4)2(OH)2Tric. 1 : P1
8.BH.CrimsonitePbFe3+2(PO4)2(OH)2Orth. mmm(2/m2/m2/m) : Cccm
8.BH.05ThadeuiteCa(Mg,Fe2+)3(PO4)2(OH,F)2Orth. 222 : C2221
8.BH.10PanasqueiraiteCaMg(PO4)(OH)Mon.
8.BH.10IsokiteCaMg(PO4)FMon. 2/m : B2/b
8.BH.10LacroixiteNaAl(PO4)FMon. 2/m : B2/b
8.BH.10ArsenatrotitaniteNaTi(AsO4)OMon. 2/m : B2/b
8.BH.10MaxwelliteNaFe3+(AsO4)FMon. 2/m : P2/m
8.BH.10DurangiteNaAl(AsO4)FMon. 2/m : B2/b
8.BH.10KononoviteNaMg(SO4)FMon. 2/m : B2/b
8.BH.15DrugmanitePb2Fe3+(PO4)(PO3OH)(OH)2Mon. 2/m : P21/b
8.BH.20Nigelcookite PbFe2+2V3+2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20Plumbojohntomaite PbFe2+2Fe3+2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20CirroliteCa3Al2(PO4)3(OH)3 (?)
8.BH.20PenikisiteBa(Mg,Fe2+,Ca)2Al2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20PerloffiteBa(Mn2+,Fe2+)2Fe3+2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20Bjarebyite Group
8.BH.20StrontioperloffiteSrMn2+2Fe3+2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20PlumboperloffitePbMn2+2Fe3+2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20JohntomaiteBaFe2+2Fe3+2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20Bjarebyite(Ba,Sr)(Mn2+,Fe2+,Mg)2Al2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.20KulaniteBa(Fe2+,Mn2+,Mg)2(Al,Fe3+)2(PO4)3(OH)3Mon. 2/m : P21/m
8.BH.25BertossaiteLi2CaAl4(PO4)4(OH)4Orth. mmm(2/m2/m2/m)
8.BH.25NatropalermoiteNa2SrAl4(PO4)4(OH)4Orth. mmm(2/m2/m2/m)
8.BH.25PalermoiteLi2SrAl4(PO4)4(OH)4Orth. mmm(2/m2/m2/m)
8.BH.30SewarditeCaFe3+2(AsO4)2(OH)2Orth. mmm(2/m2/m2/m) : Cccm
8.BH.30CarminitePbFe3+2(AsO4)2(OH)2Orth. mmm(2/m2/m2/m) : Cccm
8.BH.35AdeliteCaMg(AsO4)(OH)Orth. 222 : P212121
8.BH.35DuftitePbCu(AsO4)(OH)Orth. 222 : P212121
8.BH.35CobaltaustiniteCaCo(AsO4)(OH)Orth. 222 : P212121
8.BH.35NickelaustiniteCaNi(AsO4)(OH)Orth. 222 : P212121
8.BH.35GabrielsonitePbFe3+(As3+O3)OOrth. mm2 : Pmc21
8.BH.35ConichalciteCaCu(AsO4)(OH)Orth. 222 : P212121
8.BH.35'Duftite-alpha'PbCu(AsO4)(OH)
8.BH.35GottlobiteCaMg(VO4)(OH)Orth. 222 : P212121
8.BH.35AustiniteCaZn(AsO4)(OH)Orth. 222 : P212121
8.BH.35HermannroseiteCaCu(PO4)(OH)Orth. 222 : P212121
8.BH.35TangeiteCaCu(VO4)(OH)Orth. 222 : P212121
8.BH.40ČechitePbFe2+(VO4)(OH)Orth. mmm(2/m2/m2/m)
8.BH.40Khorixasite(Bi0.670.33)Cu(VO4)(OH)Mon. 2/m : P2/m
8.BH.40MottramitePbCu(VO4)(OH)Orth. mmm(2/m2/m2/m) : Pnma
8.BH.40DescloizitePbZn(VO4)(OH)Orth. mmm(2/m2/m2/m) : Pnma
8.BH.40PyrobelonitePbMn2+(VO4)(OH)Orth. mmm(2/m2/m2/m) : Pnma
8.BH.45BayldonitePbCu3(AsO4)2(OH)2Mon. 2/m : B2/b
8.BH.45VésigniéiteBaCu3(VO4)2(OH)2Mon. 2/m : B2/m
8.BH.50PaganoiteNiBi(AsO4)OTric. 1 : P1
8.BH.55JagoweriteBaAl2(PO4)2(OH)2Tric.
8.BH.55HarrisoniteCa(Fe2+,Mg)6(PO4)2(SiO4)2Trig. 3m(32/m) : R3m
8.BH.60AttakoliteCaMn2+Al4(SiO3OH)(PO4)3(OH)4Mon. 2/m : B2/m
8.BH.65LeningraditePbCu3(VO4)2ClOrth. mmm(2/m2/m2/m) : Ibam
8.BH.70KatiarsiteKTiO(AsO4)Orth. mm2 : Pna21
8.BH.70YurgensoniteK2SnTiO2(AsO4)2Orth. mm2 : Pna21
8.BH.75MelanarsiteK3Cu7Fe3+O4(AsO4)4Mon. 2/m : B2/b
8.BH.80EvseeviteNa2Mg(AsO4)FOrth. mmm(2/m2/m2/m) : Pbcn
8.BH.80MoraskoiteNa2Mg(PO4)FOrth. mmm(2/m2/m2/m) : Pbcn
8.BH.85PiccoliiteNaCaMn3+2(AsO4)2O(OH)Orth. mmm(2/m2/m2/m) : Pbcm

Fluorescence of ArsendescloiziteHide

Not fluorescent.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ArsendescloiziteHide

References for ArsendescloiziteHide

Localities for ArsendescloiziteHide

Showing 34 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia
 
  • South Australia
    • Pastoral Unincorporated Area
      • Puttapa
Confirmed by Peter Elliot
Austria
 
  • Lower Austria
    • Lilienfeld District
      • Annaberg
Auer et al. (2015) +1 other reference
  • Salzburg
    • Hallein District
      • Abtenau
Bernhard Kutil Collection
  • Tyrol
    • Kufstein District
      • Reith im Alpbachtal
Poeverlein +1 other reference
China
 
  • Yunnan
    • Honghe
      • Gejiu City
Baoqin Zhao (1985)
    • Kunming
Shen (n.d.)
        • Tangdan Town
          • Shizhuang Village
Shen (n.d.)
Sun et al. (2024)
Germany
 
  • Baden-Württemberg
    • Freiburg Region
      • Ortenaukreis
        • Gengenbach
          • Gengenbach
EDS and SXRD-analyzed by Joy Desor. +1 other reference
        • Seelbach
          • Seelbach
            • Weiler
Walenta (1989) +1 other reference
  • Rhineland-Palatinate
    • Rhein-Lahn-Kreis
Wittern (2001)
Greece
 
  • Attica
    • East Attica
      • Lavreotiki
        • Agios Konstantinos (Kamariza)
Schnorrer (1995) +1 other reference
          • Mercati mines
Rieck (1999)
        • Plaka
          • Plaka Mines
Indonesia
 
  • Maluku Province
    • Barat Daya Islands
      • Wetar Island
Scotney et al. (2005)
Italy
 
  • Trentino-Alto Adige/Südtirol
    • Trento Province
      • Levico Terme
Bortolozzi et al. (2021)
Japan
 
  • Miyazaki Prefecture
    • Nishiusuki District
      • Takachiho
Kato et al. (1993) +1 other reference
Mexico
 
  • Chihuahua
    • Aquiles Serdán Municipality
University of Arizona analysis
  • Durango
    • Mapimí Municipality
      • Mapimí
Wilson (1989) +1 other reference
Moore et al. (2003)
Namibia (TL)
 
  • Oshikoto Region
    • Tsumeb
Dunn et al. (1982) +1 other reference
Portugal
 
  • Beja
    • Moura
      • Sobral da Adiça
Ko Jansen collection
collection Ko Jansen +1 other reference
Slovakia
 
  • Košice Region
    • Rožňava District
      • Rochovce
Radková P. et al. (2019)
Switzerland
 
  • Valais
    • Goms
      • Binn
        • Fäld
EDXS analyses +1 other reference
Cannon et al. (2008)
UK
 
  • England
    • Cumbria
      • Allerdale
        • Caldbeck
- (2006)
USA
 
  • Arizona
    • Maricopa County
      • Osborn Mining District
        • Tonopah
          • Belmont Mountain
Collected by and in the collection of ...
  • Montana
    • Granite County
      • Philipsburg Mining District (Flint Creek Mining District)
Min News 21:7 p 1
  • Nevada
    • Humboldt County
      • Iron Point Mining District
        • Valmy
Rocks & Minerals Vol. 74 No. 6 Nov/Dec ...
    • Nye County
      • Lodi Hills
        • Lodi Mining District
          • Marble camp
Tony Nickischer (2015, #1)
    • Pershing County
      • Antelope Springs Mining District
Castor et al. (2004)
  • Washington
    • Stevens County
      • Springdale Mining District
...
 
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