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Chiavennite

A valid IMA mineral species
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About ChiavenniteHide

05778150017271922121364.jpg
The town of Chiavenna in the valley taken from Savogno.

Chiavenna, Sondrio Province, Lombardy, Italy
Formula:
CaMnBe2Si5O13(OH)2 · 2H2O
from Grice et al. (2016): Ca1-2(Mn,Fe)Si5Be2O13(OH)2.2H2O
Colour:
Pale orange-yellow
Lustre:
Vitreous, Pearly
Hardness:
3
Specific Gravity:
2.64
Crystal System:
Monoclinic
Member of:
Name:
Named by Mirella Bondi, William L. Griffin, Vittorio Mattioli, and Annibale Mottana in 1983 for the type locality of Chiavenna, Italy.
Isostructural with:
Closely related to Ferrochiavennite, which is its Fe analogue. See also the related tvedalite and another chemically close mineral, harstigite. Re-investigations of Chiavennite from the TL indicate that at room temperature chiavennite is monoclinic with spacegroup P21/c; the mineral becomes orthorhombic (Pbcn) upon dehydration due to destruction of water(extraframework)-oxygen(cavity walls) hydrogen bonds (Cametti & Armbruster 2015).

The structure is described as an interrupted framework with four-connected SiO4 and three-connected BeO4 tetrahedra, the latter closely associated with H atoms. There are 9-, 6-, 5- and 4-fold rings in it. Calcium may exist in a single site, or in two sites, of which the second one is partially occupied.

The history of the discovery of chiavennite
Chiavennite was first discovered in 1970 by the Norwegian mineralogist Reidar Åmli in a syenite pegmatite in the Heia Quarry, Tvedalen, Larvik, Vestfold, Norway. A qualitative analysis (by Per Chr. SĂŠbĂž) showed it to be a possible new mineral, a Ca-Mn-Be silicate, but due to the scarcity of the material, no further investigation was made. A few years later, in 1974, Arne Åsheim found identical material from another locality in the same area, at BlĂ„fjell (E 18 roadcuts), Kokkersvold, Porsgrunn, Telemark and a new research on the material were initiated. Independently, the same mineral was discovered in an Italian locality, Tannon, Chiavenna, Valchiavenna, Sondrio Province, Lombardy.
The Norwegian research group submitted their description with the complete data to the IMA CNMMN, on the March 4. 1981, but it turned out that the Italians, independently, had submitted their description only a few days earlier. The new mineral was approved by IMA after a joint submission of the data from the Italian and Norwegian groups.
The mineral was named chiavennite after the Italian locality, since the Italian proposal was submitted first. Descriptions on both the Italian and the Norwegian minerals were published in 1983, in the same issue of the American Mineralogist (Bondi et al. 1983, Raade et al. 1983, Raade 1996, Larsen 2001, Ciriotti et al. 2009).


Unique IdentifiersHide

Mindat ID:
1002
Long-form identifier:
mindat:1:1:1002:9

IMA Classification of ChiavenniteHide

Approved
IMA Formula:
CaMn2+(BeOH)2Si5O13·2H2O
Approval year:
1981
First published:
1983

Classification of ChiavenniteHide

9.GF.25

9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H2O; zeolite family
F : Other Rare Zeolites
70.5.1.1

70 : INOSILICATES Column or Tube Structures
5 : Column or Tube Structures with chains linked by Be
14.3.18

14 : Silicates not Containing Aluminum
3 : Silicates of Be

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
CveIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ChiavenniteHide

Vitreous, Pearly
Transparency:
Translucent
Colour:
Pale orange-yellow
Streak:
White; pale ocher
Hardness:
Cleavage:
Perfect
Good to perfect cleavages along {100}, {010}, and {001}.
Density:
2.64 g/cm3 (Measured)    2.657 g/cm3 (Calculated)

Optical Data of ChiavenniteHide

Type:
Biaxial (+)
RI values:
nα = 1.596(2) nβ = 1.600(2) nγ = 1.618(2)
2V:
Measured: 50° , Calculated: 52°
Max. Birefringence:
δ = 0.022
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 ”m thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r < v weak
Optical Extinction:
X = a, Y = b, Z = c.
Pleochroism:
Visible
Comments:
X = colorless to pale yellow; Z = yellow-orange.

Chemistry of ChiavenniteHide

Mindat Formula:
CaMnBe2Si5O13(OH)2 · 2H2O

from Grice et al. (2016): Ca1-2(Mn,Fe)Si5Be2O13(OH)2.2H2O
Element Weights:
Element% weight
O51.174 %
Si26.421 %
Mn10.336 %
Ca7.541 %
Be3.391 %
H1.138 %

Calculated from ideal end-member formula.
O
Si
Mn
Ca
Be
H
Common Impurities:
Al,Fe,Mg,Ca,Na,K,F,C

Chemical AnalysisHide

Oxide wt%:
 12
SiO250.0 %52.5 %
Al2O36.76 %3.6 %
BeO8.72 %9.3 %
FeO2.01 %
MnO10.6 %12.9 %
MgO0.14 %
CaO9.69 %10.2 %
Na2O0.68 %0.3 %
K2O0.04 %
H2O10.4 %11.3 %
CO20.83 %
F0.21 %
Total:100.08 %100.1 %
Empirical formulas:
Sample IDEmpirical Formula
1(Ca0.97Na0.05)ÎŁ1.02Mn0.97(Be1.98Al0.03)ÎŁ2.01(Si4.65Al0.35)ÎŁ5.00O12.63(OH2.37) *2H2O
2(Ca0.97Na0.05) ÎŁ1.02Mn0.97(Be1.98Al0.03)ÎŁ2.01(Si4.65Al0.35)ÎŁ5.00O12.63(OH)2.37* 2.16H2O

Crystallography of ChiavenniteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/c
Setting:
P21/c
Cell Parameters:
a = 8.7466(3) Å, b = 4.8972(3) Å, c = 31.3160(16) Å
β = 90.128(4)°
Ratio:
a:b:c = 1.786 : 1 : 6.395
Unit Cell V:
1341.39 ų
Morphology:
Crystals from the TL are showing a flat pseudohexagonal habit. From Larvik Plutonic Complex (Langesundsfjorden area), Norway: Spherulitic aggregates concisting of spear-shaped crystals, flattened on {010}, terminated by the orthorhombic pyramid {161}.
Twinning:
Common, on {100}.
Comment:
Previously reported to be orthorhombic; unit cell parameters for the orthorhombic dehydrated phase, i.e., at 425oC, of the Pbcn cell, transformed in (non-standard) Pnca setting: a=8.6795(15), b=4.9017(10), c=31.513(6).

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0006609ChiavenniteTazzoli V, Domeneghetti M C, Mazzi F, Cannillo E (1995) The crystal structure of chiavennite European Journal of Mineralogy 7 1339-133419950293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
15.77 Å(100bb)
4.15 Å(30)
3.93 Å(30b)
3.82 Å(30)
3.28 Å(75)
2.903 Å(100)
1.944 Å(30)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
22 : Hydration and low-? subsurface aqueous alteration (see also #23)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks
Geological Setting:
Alkaline syenite pegmatites and granite pegmatites

Type Occurrence of ChiavenniteHide

General Appearance of Type Material:
As euhedral orange grains and as crusts coating beryl.
Place of Conservation of Type Material:
Mineralogical-Geological Museum, University of Oslo, Oslo, Norway, numbers 22090, 22091 (cotype).
Istituto di Mineralogia e Petrografia dell’Università, Cita Universitaria, Rome, Italy, number 24342 (type).
National Museum of Natural History, Washington, D.C., USA, number 159917.
Musée Géologique Cantonal, Lausanne, Switzerland, number MGL 90755 (type).
Empirical Formula of Type Material:
(Ca0.97Na0.05) ÎŁ1.02Mn0.97(Be1.98Al0.03)ÎŁ2.01(Si4.65Al0.35)ÎŁ5.00O12.63(OH)2.37* 2.16H2O
Geological Setting of Type Material:
Alpine pegmatites (25-27 m.y.).
Associated Minerals at Type Locality:

Synonyms of ChiavenniteHide

Other Language Names for ChiavenniteHide

Relationship of Chiavennite to other SpeciesHide

Member of:
Other Members of Zeolite Group:
AlflarseniteNaCa2Be3Si4O13(OH) · 2H2OMon. 2 : P21
AmiciteK2Na2Al4Si4O16 · 5H2OMon. 2
Ammonioleucite(NH4)(AlSi2O6)Tet. 4/m : I41/a
AnalcimeNa(AlSi2O6) · H2OTric. 1 : P1
ArzamastseviteK6Al5Si6O20(OH)4ClTet. 42m : I42m
Bellbergite(K,Ba,Sr)2Sr2Ca2(Ca,Na)4[Al3Si3O12]6 · 30H2OHex.
BikitaiteLiAlSi2O6 · H2OTric. 1 : P1
BoggsiteCa8Na3(Si,Al)96O192 · 70H2OOrth. mmm(2/m2/m2/m) : Imma
Brewsterite SubgroupZeolite Group.
Chabazite-Levyne SubgroupM[Al2Si4O12] · 6H2O
Clinoptilolite Subgroup(Na/Ca/K)3-6[Al6-7Si29-30O72] · 20H2O
CowlesiteCaAl2Si3O10 · 6H2OOrth. mmm(2/m2/m2/m)
Dachiardite SubgroupZeolite Group.
DirenzoiteNaK6MgCa2(Al13Si47O120) · 36H2OOrth. mmm(2/m2/m2/m) : Pmmn
EdingtoniteBa[Al2Si3O10] · 4H2OOrth. 222 : P212121
EpistilbiteCaAl2Si6O16 · 5H2OMon.
Erionite SubgroupM2[Al4Si14O36] · 15H2O
FabriÚsiteNa3Al3Si3O12 · 2H2OOrth. mm2 : Pmm2
Faujasite SubgroupM3.5[Al7Si17O48] · 32H2O
Ferrierite SubgroupName used for unanalysed specimens that could be either ferrierite-K, ferrierite-Mg, ...
FerrochiavenniteCa1-2Fe[(Si,Al,Be)5Be2O13(OH)2] · 2H2OMon. 2/m : P21/c
Flörkeite(K3Ca2Na)[Al8Si8O32] · 12H2OTric. 1 : P1
Garronite Subgroup
GaultiteNa4Zn2Si7O18 · 5H2OOrth. mm2 : Fdd2
Gismondine SubgroupZeolite Group.
Gmelinite SubgroupIn 1997, gmelinite was split into Gmelinite-Ca, Gmelinite-Na and Gmelinite-K.
GobbinsiteNa5(Si11Al5)O32 · 11H2OOrth. mmm(2/m2/m2/m) : Pnma
GoosecreekiteCa[Al2Si6O16] · 5H2OMon. 2 : P21
GottardiiteNa3Mg3Ca5Al19Si117O272 · 93H2OOrth. mmm(2/m2/m2/m) : Cmca
Heulandite Subgroup(Na/Ca/K)5-6[Al8-9 Si27-28 O72] · nH2O
HsianghualiteCa3Li2(Be3Si3O12)F2Iso. 23 : I213
KalborsiteK6Al4BSi6O20(OH)4ClTet. 42m : P421c
KirchhoffiteCs(BSi2O6)Tet. 4/mmm(4/m2/m2/m) : I41/acd
LaumontiteCaAl2Si4O12 · 4H2OMon. 2/m : B2/m
LeuciteK(AlSi2O6)Tet. 4/m : I41/a
LimousiniteBaCa[Be4P4O16] · 6H2OMon. 2/m : P21/c
LithositeK6Al4Si8O25 · 2H2OMon.
Loomisite Ba[Be2P2O8] · H2OMon. m
LovdariteK2Na6Be4Si14O36 · 9H2OOrth. mm2
MaricopaitePb7Ca2(Si,Al)48O100 · 32H2OOrth.
MartinandresiteBa2(Al4Si12O32) · 10H2OOrth. mmm(2/m2/m2/m) : Pmmn
Mazzite SubgroupZeolite Group.
MeieriteBa44Si66Al30O192Cl25(OH)33Iso. m3m(4/m32/m) : Im3m
MerlinoiteK5Ca2(Si23Al9)O64 · 24H2OOrth. mmm(2/m2/m2/m) : Immm
Montesommaite(K,Na)9Al9Si23O64 · 10H2OOrth. mm2 : Fdd2
Mordenite(Na2,Ca,K2)4(Al8Si40)O96 · 28H2OOrth.
MountainiteKNa2Ca2[Si8O19(OH)] · 6H2OMon. 2/m : P2/b
MutinaiteNa3Ca4Si85Al11O192 · 60H2OOrth. mmm(2/m2/m2/m) : Pnma
NabesiteNa2BeSi4O10 · 4H2OOrth. 222 : P212121
Natrolite SubgroupA subgroup of the Zeolite Group.
OffretiteKCaMg(Si13Al5)O36 · 15H2OHex. 6m2 : P6m2
PahasapaiteLi8(Ca,Li,K)10.5Be24(PO4)24 · 38H2OIso. 23 : I23
ParthéiteCa2(Si4Al4) O15 (OH)2 · 4H2OMon. 2/m : B2/b
Paulingite SubgroupPaulingite was originally described in 1960.
PerlialiteK9Na(Ca,Sr)[Al2Si4O12]6 · 15H2OHex. 6/mmm(6/m2/m2/m) : P6/mmm
Phillipsite Subgroup(Ca0.5,K,Na,Ba0.5)4-7[Al4-7Si12-9O32] . 12H2O
Pollucite(Cs,Na)2(Al2Si4O12) · 2H2OIso. m3m(4/m32/m) : Ia3d
RoggianiteCa2Be(OH)2Al2Si4O13 · 2.5H2OTet. 4/mmm(4/m2/m2/m) : I4/mcm
RongibbsitePb2(Si4Al)O11(OH) Mon. 2/m : B2/m
Stilbite SubgroupM6-7[Al8-9Si27-28O72] · nH2O
Terranovaite(Na,Ca)8(Si68Al12)O160 · 29H2OOrth.
Thomsonite SubgroupThe large majority of "thomsonite" is thomsonite-Ca.
ThornasiteNa12Th4+3(Si8O19)4 · 18H2OTrig. 3m : R3m
Tschernichite(Ca,Na2)[Al2Si4O12] · 4-8H2OTet. 4/mmm(4/m2/m2/m) : P4/mmm
TschörtneriteCa4(Ca,Sr,K,Ba)3Cu3[Al3Si3O12]4(OH)8 · nH2OIso. m3m(4/m32/m) : Fm3m
'UM1996-38-SiO:AlCaHNa'Na-Ca-Al-Si-O-H
'UM1999-33-SiO:AlHKNa'K7Na5Al12Si20O64 · 24H2O
'UM2002-40-SiO:AlCaHKMgNa'(Mg,Ca,Na,K)7.5(Al12.8Si51.2)O128 · 65H2OTet. 422 : P4122
'Unnamed (Ca analogue of Merlinoite)'(Ca,K,Na)5(Ca,Ba)2Al9Si23O64 · 23H2O ?
WairakiteCa(Al2Si4O12) · 2H2OMon. 2/m : B2/b
WeinebeneiteCaBe3(PO4)2(OH)2 · 4H2OMon. m : Bb
Wenkite(Ba,K)4(Ca,Na)6[(Si,Al)20O39(OH)2](SO4)3 · 0.5H2OHex. 6m2 : P62m
Wilancookite(Ba5Li2◻)Ba6Be24P24O96 · 26H2OIso. 23 : I23
WillhendersoniteKCa[Al3Si3O12] · 5H2OTric. 1 : P1
YugawaraliteCaAl2Si6O16 · 4H2OMon. m : Pb

Common AssociatesHide

Associations Based on Photo Data:
50 photos of Chiavennite associated with AnalcimeNa(AlSi2O6) · H2O
33 photos of Chiavennite associated with NatroliteNa2Al2Si3O10 · 2H2O
30 photos of Chiavennite associated with AegirineNaFe3+Si2O6
12 photos of Chiavennite associated with Tvedalite(Ca,Mn)4Be3Si6O17(OH)4 · 3H2O
12 photos of Chiavennite associated with EpididymiteNa2Be2Si6O15 · H2O
12 photos of Chiavennite associated with Pezzottaite-(Cs)Cs(Be2Li)Al2(Si6O18)
12 photos of Chiavennite associated with SphaerobertranditeBe3(SiO4)(OH)2
10 photos of Chiavennite associated with CalciteCaCO3
7 photos of Chiavennite associated with CassiteriteSnO2
6 photos of Chiavennite associated with 'Chalcedony'SiO2

Related Minerals - Strunz-mindat GroupingHide

9.GF.05Terranovaite(Na,Ca)8(Si68Al12)O160 · 29H2OOrth.
9.GF.10GottardiiteNa3Mg3Ca5Al19Si117O272 · 93H2OOrth. mmm(2/m2/m2/m) : Cmca
9.GF.15LovdariteK2Na6Be4Si14O36 · 9H2OOrth. mm2
9.GF.20GaultiteNa4Zn2Si7O18 · 5H2OOrth. mm2 : Fdd2
9.GF.25FerrochiavenniteCa1-2Fe[(Si,Al,Be)5Be2O13(OH)2] · 2H2OMon. 2/m : P21/c
9.GF.30Tschernichite(Ca,Na2)[Al2Si4O12] · 4-8H2OTet. 4/mmm(4/m2/m2/m) : P4/mmm
9.GF.35MutinaiteNa3Ca4Si85Al11O192 · 60H2OOrth. mmm(2/m2/m2/m) : Pnma
9.GF.40TschörtneriteCa4(Ca,Sr,K,Ba)3Cu3[Al3Si3O12]4(OH)8 · nH2OIso. m3m(4/m32/m) : Fm3m
9.GF.55DirenzoiteNaK6MgCa2(Al13Si47O120) · 36H2OOrth. mmm(2/m2/m2/m) : Pmmn
9.GF.60MeieriteBa44Si66Al30O192Cl25(OH)33Iso. m3m(4/m32/m) : Im3m
9.GF.65RongibbsitePb2(Si4Al)O11(OH) Mon. 2/m : B2/m

Other InformationHide

Thermal Behaviour:
Continuous water loss up to ca. 452°C not associated with topological modification; at 250°C more than a single water molecule is lost, in association with LKCa lowering from 8 to 7.
Notes:
Insoluble in water, and in concentrated HCl, HNO3 and H2SO4.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ChiavenniteHide

References for ChiavenniteHide

Reference List:

Localities for ChiavenniteHide

Showing 33 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Hide all sections | Show all sections

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Italy (TL)
 
  • Lombardy
    • Sondrio Province
      • Chiavenna
Bondi et al. (1983) +1 other reference
      • Prata Camportaccio
Pezzotta et al. (2004)
Madagascar
 
  • Amoron'i Mania
    • Ambatofinandrahana District
      • Mandrosonoro
        • Ambatovita
Pezzotta et al. (2004) +1 other reference
Mexico
 
  • San Luis PotosĂ­
    • Rioverde Municipality
Planer-Friedrich (2000)
Norway
 
  • Telemark
    • Porsgrunn
      • Auenlandet
        • SagĂ„sen
Engvoldsen et al. (1991)
Larsen et al. (2005)
      • Langangen
        • Kokkersvold - BlĂ„fjell E18 roadcuts
Raade et al. (1983)
Raade et al. (1983)
Larsen (1988) +1 other reference
  • Vestfold
    • Larvik Commune
      • Brunlanes
Raade et al. (1983)
      • Hedrum
        • LĂ„gendalen
Andersen (1993) +1 other reference
      • MalerĂžd
Andresen (2011)
      • TjĂžlling
        • KlĂ„stad
Sunde et al. (2020)
BjĂžrn K. Stensvold collection +1 other reference
      • Tvedalen
Engvoldsen et al. (1991)
Larsen et al. (2010)
Berge (1993)
Raade et al. (1983) +1 other reference
Peter Andresen collection
Larsen et al. (2010)
Berge (1993) +1 other reference
Engvoldsen et al. (1991) +1 other reference
Nordrum (2008)
- (n.d.) +1 other reference
Knut Edvard Larsen observation and ...
Raade et al. (1983) +1 other reference
      • Vesle ArĂžya
Berge (1993) +3 other references
Spain
 
  • Canary Islands
    • Santa Cruz de Tenerife Province
      • Tenerife
        • Arico
Dill et al. (2023)
Dill et al. (2023)
Dill et al. (2023)
        • Santiago del Teide
Dill et al. (2023)
Sweden
 
  • Stockholm County
    • Haninge
      • Utö
Langhof et al. (1998) +1 other reference
Nysten (1996)
 
and/or  
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To cite: Ralph, J., Von Bargen, D., Martynov, P., Zhang, J., Que, X., Prabhu, A., Morrison, S. M., Li, W., Chen, W., & Ma, X. (2025). Mindat.org: The open access mineralogy database to accelerate data-intensive geoscience research. American Mineralogist, 110(6), 833–844. doi:10.2138/am-2024-9486.
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