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Direnzoite

A valid IMA mineral species
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03225890017271949499171.jpg
Francesco Di Renzo
Formula:
NaK6MgCa2(Al13Si47O120) · 36H2O
Colour:
Colourless
Lustre:
Vitreous, Silky
Hardness:
4½
Specific Gravity:
2.12
Crystal System:
Orthorhombic
Member of:
Zeolite Group
Name:
Named for Dr Francesco Di Renzo (1954- ), Research Director at the Laboratoire de Materiaux, Catalytiques et Catalyse en Chimie Organique, Ecole Nationale Superieure de Chimie de Montpellier, France. He is an expert in the field of zeolites, mesoporous materials, and catalysis.
This page provides mineralogical data about Direnzoite.


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Unique IdentifiersHide

Mindat ID:
31408
Long-form identifier:
mindat:1:1:31408:8

IMA Classification of DirenzoiteHide

Classification of DirenzoiteHide

Strunz-mindat (2026):
9.GF.55

9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H2O; zeolite family
F : Other Rare Zeolites
Dana 7th ed.:
77.1.44.1

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
DrzIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of DirenzoiteHide

Lustre:
Vitreous, Silky
Transparency:
Transparent, Translucent
Colour:
Colourless
Streak:
White
Hardness:
4½ on Mohs scale
Hardness Data:
Estimated
Comment:
estimated as mean value between that of mordenite & mazzite
Tenacity:
Brittle
Cleavage:
Distinct/Good
along the [010]
Fracture:
Splintery
Density:
2.12(3) g/cm3 (Measured)    2.080(5) g/cm3 (Calculated)

Chemistry of DirenzoiteHide

Mindat Formula:
NaK6MgCa2(Al13Si47O120) · 36H2O
Element Weights:
Element% weight
O54.244 %
Si28.688 %
Al7.623 %
K5.098 %
Ca1.742 %
H1.577 %
Mg0.528 %
Na0.500 %

Calculated from ideal end-member formula.
Elements listed:
Al, Ca, H, K, Mg, Na, O, Si - search for minerals with similar chemistry

Crystallography of DirenzoiteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Pmmn
Cell Parameters:
a = 7.57887(18) Å, b = 18.20098(57) Å, c = 26.15387(83) Å
Ratio:
a:b:c = 0.416 : 1 : 1.437
Unit Cell V:
3607.74 ų

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0004494DirenzoiteGalli E, Gualtieri A F (2008) Direnzoite, [NaK6MgCa2(Al13Si47O120)*36H2O], a new zeolite from Massif Central (France): Description and crystal structure American Mineralogist 93 95-1022008Massif Central, France0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3a: Earth’s earliest Hadean crust>4.50
10 : Basalt-hosted zeolite minerals

Type Occurrence of DirenzoiteHide

Type Locality:
ⓘ Mont Peylenc quarry, Saint-Pierre-Eynac, Le Puy-en-Velay, Haute-Loire, Auvergne-Rhône-Alpes, France
General Appearance of Type Material:
Spherical aggregates of fibrous micro-crystals.
Place of Conservation of Type Material:
not given in article
Geological Setting of Type Material:
Found in cavities of a xenolitic rock
Reference:
Galli, E., Gualtieri, A.F. (2008) Direnzoite, [NaK6MgCa2(Al13Si47O120)·36H2O], a new zeolite from Massif Central (France): Description and crystal structure. American Mineralogist, 93 (1) 95-102 doi:10.2138/am.2008.2666

Synonyms of DirenzoiteHide

Other Language Names for DirenzoiteHide

German:Direnzoit
Spanish:Direnzoíta

Relationship of Direnzoite to other SpeciesHide

Member of:
Zeolite Group
Other Members of Zeolite Group:
AlflarseniteNaCa2Be3Si4O13(OH) · 2H2OMon. 2 : P21
AmiciteK2Na2Al4Si4O16 · 5H2OMon. 2
Ammonioleucite(NH4)(AlSi2O6)Tet. 4/m : I41/a
AnalcimeNa(AlSi2O6) · H2OTric. 1 : P1
ArzamastseviteK6Al5Si6O20(OH)4ClTet. 42m : I42m
Bellbergite(K,Ba,Sr)2Sr2Ca2(Ca,Na)4[Al3Si3O12]6 · 30H2OHex.
BikitaiteLiAlSi2O6 · H2OTric. 1 : P1
BoggsiteCa8Na3(Si,Al)96O192 · 70H2OOrth. mmm(2/m2/m2/m) : Imma
Brewsterite SubgroupZeolite Group.
Chabazite-Levyne SubgroupM[Al2Si4O12] · 6H2O
ChiavenniteCaMnBe2Si5O13(OH)2 · 2H2OMon. 2/m : P21/b
Clinoptilolite Subgroup(Na/Ca/K)3-6[Al6-7Si29-30O72] · 20H2O
CowlesiteCaAl2Si3O10 · 6H2OOrth. mmm(2/m2/m2/m)
Dachiardite SubgroupZeolite Group.
EdingtoniteBa[Al2Si3O10] · 4H2OOrth. 222 : P212121
EpistilbiteCaAl2Si6O16 · 5H2OMon.
Erionite SubgroupM2[Al4Si14O36] · 15H2O
FabrièsiteNa3Al3Si3O12 · 2H2OOrth. mm2 : Pmm2
Faujasite SubgroupM3.5[Al7Si17O48] · 32H2O
Ferrierite SubgroupName used for unanalysed specimens that could be either ferrierite-K, ferrierite-Mg, ...
FerrochiavenniteCa1-2Fe[(Si,Al,Be)5Be2O13(OH)2] · 2H2OMon. 2/m : P21/b
Flörkeite(K3Ca2Na)[Al8Si8O32] · 12H2OTric. 1 : P1
Garronite Subgroup
GaultiteNa4Zn2Si7O18 · 5H2OOrth. mm2 : Fdd2
Gismondine SubgroupZeolite Group.
Gmelinite SubgroupIn 1997, gmelinite was split into Gmelinite-Ca, Gmelinite-Na and Gmelinite-K.
GobbinsiteNa5(Si11Al5)O32 · 11H2OOrth. mmm(2/m2/m2/m) : Pnma
GoosecreekiteCa[Al2Si6O16] · 5H2OMon. 2 : P21
GottardiiteNa3Mg3Ca5Al19Si117O272 · 93H2OOrth. mmm(2/m2/m2/m) : Cmca
Heulandite Subgroup(Na/Ca/K)5-6[Al8-9 Si27-28 O72] · nH2O
HsianghualiteCa3Li2(Be3Si3O12)F2Iso. 23 : I213
KalborsiteK6Al4BSi6O20(OH)4ClTet. 42m : P421c
KirchhoffiteCs(BSi2O6)Tet. 4/mmm(4/m2/m2/m) : I41/acd
LaumontiteCaAl2Si4O12 · 4H2OMon. 2/m : B2/m
LeuciteK(AlSi2O6)Tet. 4/m : I41/a
LimousiniteBaCa[Be4P4O16] · 6H2OMon. 2/m : P21/b
LithositeK6Al4Si8O25 · 2H2OMon.
Loomisite Ba[Be2P2O8] · H2OMon. m
LovdariteK2Na6Be4Si14O36 · 9H2OOrth. mm2
MaricopaitePb7Ca2(Si,Al)48O100 · 32H2OOrth.
MartinandresiteBa2(Al4Si12O32) · 10H2OOrth. mmm(2/m2/m2/m) : Pmmn
Mazzite SubgroupZeolite Group.
MeieriteBa44Si66Al30O192Cl25(OH)33Iso. m3m(4/m32/m) : Im3m
MerlinoiteK5Ca2(Si23Al9)O64 · 24H2OOrth. mmm(2/m2/m2/m) : Immm
Montesommaite(K,Na)9Al9Si23O64 · 10H2OOrth. mm2 : Fdd2
Mordenite(Na2,Ca,K2)4(Al8Si40)O96 · 28H2OOrth.
MountainiteKNa2Ca2[Si8O19(OH)] · 6H2OMon. 2/m : P2/b
MutinaiteNa3Ca4Si85Al11O192 · 60H2OOrth. mmm(2/m2/m2/m) : Pnma
NabesiteNa2BeSi4O10 · 4H2OOrth. 222 : P212121
Natrolite SubgroupA subgroup of the Zeolite Group.
OffretiteKCaMg(Si13Al5)O36 · 15H2OHex. 6m2 : P6m2
PahasapaiteLi8(Ca,Li,K)10.5Be24(PO4)24 · 38H2OIso. 23 : I23
ParthéiteCa2(Si4Al4) O15 (OH)2 · 4H2OMon. 2/m : B2/b
Paulingite SubgroupPaulingite was originally described in 1960.
PerlialiteK9Na(Ca,Sr)[Al2Si4O12]6 · 15H2OHex. 6/mmm(6/m2/m2/m) : P6/mmm
Phillipsite Subgroup(Ca0.5,K,Na,Ba0.5)4-7[Al4-7Si12-9O32] . 12H2O
Pollucite(Cs,Na)2(Al2Si4O12) · 2H2OIso. m3m(4/m32/m) : Ia3d
RoggianiteCa2Be(OH)2Al2Si4O13 · 2.5H2OTet. 4/mmm(4/m2/m2/m) : I4/mcm
RongibbsitePb2(Si4Al)O11(OH) Mon. 2/m : B2/m
Stilbite SubgroupM6-7[Al8-9Si27-28O72] · nH2O
Terranovaite(Na,Ca)8(Si68Al12)O160 · 29H2OOrth.
Thomsonite SubgroupThe large majority of "thomsonite" is thomsonite-Ca.
ThornasiteNa12Th4+3(Si8O19)4 · 18H2OTrig. 3m : R3m
Tschernichite(Ca,Na2)[Al2Si4O12] · 4-8H2OTet. 4/mmm(4/m2/m2/m) : P4/mmm
TschörtneriteCa4(Ca,Sr,K,Ba)3Cu3[Al3Si3O12]4(OH)8 · nH2OIso. m3m(4/m32/m) : Fm3m
'UM1996-38-SiO:AlCaHNa'Na-Ca-Al-Si-O-H
'UM1999-33-SiO:AlHKNa'K7Na5Al12Si20O64 · 24H2O
'UM2002-40-SiO:AlCaHKMgNa'(Mg,Ca,Na,K)7.5(Al12.8Si51.2)O128 · 65H2OTet. 422 : P4122
'Unnamed (Ca analogue of Merlinoite)'(Ca,K,Na)5(Ca,Ba)2Al9Si23O64 · 23H2O ?
WairakiteCa(Al2Si4O12) · 2H2OMon. 2/m : B2/m
WeinebeneiteCaBe3(PO4)2(OH)2 · 4H2OMon. m : Bb
Wenkite(Ba,K)4(Ca,Na)6[(Si,Al)20O39(OH)2](SO4)3 · 0.5H2OHex. 6m2 : P62m
Wilancookite(Ba5Li2◻)Ba6Be24P24O96 · 26H2OIso. 23 : I23
WillhendersoniteKCa[Al3Si3O12] · 5H2OTric. 1 : P1
YugawaraliteCaAl2Si6O16 · 4H2OMon. m : Pb

Related Minerals - Strunz-mindat GroupingHide

9.GF.05Terranovaite(Na,Ca)8(Si68Al12)O160 · 29H2OOrth.
9.GF.10GottardiiteNa3Mg3Ca5Al19Si117O272 · 93H2OOrth. mmm(2/m2/m2/m) : Cmca
9.GF.15LovdariteK2Na6Be4Si14O36 · 9H2OOrth. mm2
9.GF.20GaultiteNa4Zn2Si7O18 · 5H2OOrth. mm2 : Fdd2
9.GF.25FerrochiavenniteCa1-2Fe[(Si,Al,Be)5Be2O13(OH)2] · 2H2OMon. 2/m : P21/b
9.GF.25ChiavenniteCaMnBe2Si5O13(OH)2 · 2H2OMon. 2/m : P21/b
9.GF.30Tschernichite(Ca,Na2)[Al2Si4O12] · 4-8H2OTet. 4/mmm(4/m2/m2/m) : P4/mmm
9.GF.35MutinaiteNa3Ca4Si85Al11O192 · 60H2OOrth. mmm(2/m2/m2/m) : Pnma
9.GF.40TschörtneriteCa4(Ca,Sr,K,Ba)3Cu3[Al3Si3O12]4(OH)8 · nH2OIso. m3m(4/m32/m) : Fm3m
9.GF.60MeieriteBa44Si66Al30O192Cl25(OH)33Iso. m3m(4/m32/m) : Im3m
9.GF.65RongibbsitePb2(Si4Al)O11(OH) Mon. 2/m : B2/m

RadioactivityHide

Radioactivity:
Element % Content Activity (Bq/kg) Radiation Type
Uranium (U) 0.0000% 0 α, β, γ
Thorium (Th) 0.0000% 0 α, β, γ
Potassium (K) 5.0983% 1,580 β, γ

For comparison:

  • Banana: ~15 Bq per fruit
  • Granite: 1,000–3,000 Bq/kg
  • EU exemption limit: 10,000 Bq/kg

Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.

Interactive Simulator:

Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!

Activity: –

DistanceDose rateRisk
1 cm
10 cm
1 m

The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for DirenzoiteHide

References for DirenzoiteHide

Localities for DirenzoiteHide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
France (TL)
 
  • Auvergne-Rhône-Alpes
    • Haute-Loire
      • Le Puy-en-Velay
        • Saint-Pierre-Eynac
Galli et al. (2008)
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